J.R. S. answered 05/17/22
Ph.D. University Professor with 10+ years Tutoring Experience
H2 + Cl2 ==> 2HCl ... balanced equation
You can read this reaction in a number of different ways
1 mol H2 reacts with 1 mol Cl2 to produce 2 mols HCl
1 liter H2 reacts with 1 liter Cl2 to produce 2 liters HCl
1 molecule H2 reacts with 1 molecule Cl2 to produce 1 molecule HCl
etc, etc.
Using the relationship that 1 liter of H2 reacts with 1 liter of Cl2 to produce 2 liters of HCl,...
Because we are given the volumes of BOTH reactants (H2 and Cl2), we have to find the limiting reactant. In this case it will be Cl2 since you have only 4 liters of Cl2 but we have 6 liters of H2. Cl2 will run out first.
The limiting reactant will determine the amount of product that can be formed
4 L Cl2 x 2 L HCl / 1 L Cl2 = 8 L HCl = volume of HCl formed