J.R. S. answered 05/01/22
Ph.D. University Professor with 10+ years Tutoring Experience
Total pressure = partial pressure CO2 + partial pressure N2 (Dalton's Law)
Mole fraction x Total pressure = partial pressure of the gas
a.
1). Find total mols of gas present:
PV = nRT and solve for n
n = PV/RT = (29.75 atm)(15.90 L) / (0.0821 Latm/Kmol)(308K)
n = 18.71 mols of gas
2). Find moles of CO2:
18.706 mols - 7.152 mols N2 = 11.55 mols CO2
3). Determine partial pressure of CO2:
partial pressure CO2 = mol fraction CO2 x Total pressure
mole fraction of CO2 = mols CO2 / mols CO2 + mols N2 = 11.55 mols / 18.706 mls = 0.6177
partial pressure CO2 = 0.6177 x 29.75 atm = 18.38 atm
b.
1). Find total mols of gas:
Total moles = 1.850 mol NO2 + 2.29 mols CH4 + 3.01 mols Ne = 7.15 mols
2). Find mol fraction of each gas:
mol fraction of a gas = moles of gas / total moles
mol fraction NO2 = 1.85 / 7.15 = 0.259
mol fraction CH4 = 2.29 / 7.15 = 0.320
mol fraction Ne = 3.01 / 7.15 = 0.421