J.R. S. answered 04/21/22
Ph.D. University Professor with 10+ years Tutoring Experience
H2SO4(aq) + Pb(C2H3O2)2(aq) ==> PbSO4(s + 2 HC2H3O2(aq) ... balanced equation
Since you are given the amounts of BOTH reactants, you must find which one is in limiting supply. An easy way to do this is to divide the MOLES of each reactant by its corresponding coefficient in the balanced equation and whichever value is less identifies the limiting reactant (see below).
For H2SO4: 16.7 g H2SO4 x 1 mol / 98 g = 0.170 moles H2SO4 (÷1->0.17)
For Pb(C2H3O2)2: 11.4 Pb(C2H3O2)2 x 1 mol / 325 g = 0.0351 moles Pb(C2H3O2)2 (÷1->0.035)
Since 0.035 is less than 0.17, lead acetate, Pb(C2H3O2)2 is the limiting reactant.
Next, the moles of the limiting reactant (0.0351 mols) will determine how many moles of H2SO4 are used and therefore, how many moles / grams of H2SO4 are left over. Since lead acetate is limiting, all of it will be used up and there will be none of left over.
To calculate grams H2SO4 left over ...
0.0351 mols lead acetate x 1 mol H2SO4 / mol lead acetate= 0.0351 mols H2SO4 used
0.170 mols H2SO4 - 0.0351 mols = 0.135 mols H2SO4 left over
mass of H2SO4 left over = 0.135 mols H2SO4 x 98 g / mol = 13.2 g H2SO4 left over
To find grams PbSO4 produced ....
0.0351 mols lead acetate x 1 mol PbSO4 / mol lead acetate x 303 g PbSO4 / mol = 10.6 g PbSO4
To find grams of acetic acid (HC2H3O2) produced:
0.0351 mols lead acetate x 2 mols HC2H3O2 / mol lead acetate x 60.1 g HC2H3O2 /mol = 4.22 g HC2H3O2