The time between occurrences, x, is often modeled by the exponential cumulative distribution:
P(x>a) = exp(-a / θ)
where θ is both the population mean (mu) and the population standard deviation (sigma).
So,
P(x>21) = exp(-21/7) = exp(-3) = 0.050
a 5% probability of going more than 21 days without an accident when the mean time between them is 7 days.