
Marc M. answered 03/16/22
Associate Professor (Oxford PhD) Genetics, Mol. Bio. and Writing Tutor
The NaCl solution is 21.7g / 653ml
or 33.231g / 1L (divide 21.7g by 0.653 liter)
A 1 molar solution of NaCl is 58.44g / 1L (This is based on the molecular weight of NaCl)
To figure out what the molarity of the solution in question is you want to know the ratio between the unknown solution and the 1molar solution.
58.44*X = 33.231 . . .
X = 33.231/58.44
X = 0.568
or 568mM (millimolar)
Once you know that the unknown solution is 33.231g / 1L you get a ballpark idea of what the molarity is when you compare to the 1molar solution of 58.44g / 1L. Just by looking at the numbers you can see it's a little more than half as much NaCl so you know the answer should be in the 0.5M to 0.6M range.