J.R. S. answered 02/24/22
Ph.D. University Professor with 10+ years Tutoring Experience
Baking soda = NaHCO3 (sodium bicarbonate)
Acetic acid = CH3COOH
NaHCO3 + CH3COOH ==> CO2 + CH3COONa + H2O ... balanced equation
An easy way to find the limiting reactant is to divide the moles of each reactant by the corresponding coefficient in the balanced equation.
For NaHCO3: 1.000 g NaHCO3 x 1 mol NaHCO3 / 84.00 g = 0.01190 mols (÷1->0.01190)
For CH3COOH: 1.500 ml x 1 L / 1000 ml x 3.00 mol/L = 0.004500 mols (÷1->0.0045)
Since 0.0045 is less than 0.0119, CH3COOH IS LIMITING
Use the mols of the limiting reactant to find the mols of CO2 (theoretical yield in mols):
0.004500 mols CH3COOH x 1 mol CO2 / mol CH3COOH = 0.004500 mols CO2
To find the volume of CO2 (in mls) @20.3ºC and 1.01 atm pressure, use the ideal gas law:
PV = nRT
P = pressure = 1.01 atm
V = volume in L = ?
n = mols = 0.004500 mols
R = gas constant = 0.0821 Latm/Kmol
T = temperature in Kelvin = 20.3ºC + 273.15 = 293.5K
Solving for V ...
V = nRT/P = (0.0045)(0.0821)(293.5) / 1.01
V = 0.107 L x 1000 ml / L = 107 ml