J.R. S. answered 01/27/22
Ph.D. University Professor with 10+ years Tutoring Experience
CaCl2 is an ionic compound.
[ Cl- ] [ Ca2+ ] [ Cl- ] and put 4 lone pairs of electrons (8 electrons) around each Cl- ion, and no electrons on the Ca2+. The shape is linear with "bond" angles of 180º
NH3: 8 valence electrons
Put N in the center and 3 N atoms single bonded to the N. Place 1 lone pair of electrons (2 electrons) on the central N atom. That uses all 8 valence electrons.
The shape (geometry) is trigonal pyramidal and the bond angle is <109.5º or ~107º
SF6: 48 valence electrons and S can violate the octet rule
Place S in the center with 6 F atoms single bonded to the S atom. Place 3 lone pairs of electrons (6 electrons) around each F atom. That uses all 48 valence electrons. The shape (geometry) is octahedral and the bond angle is 90º