J.R. S. answered 12/19/21
Ph.D. University Professor with 10+ years Tutoring Experience
I’ll assume the question is asking for exactly 500 mls of 0.345 M H2SO4.
molar mass H2SO4 = 98.08 g/mol
0.345 M = 0.345 mol/L
To make 500 mls (0.500 L) you need 0.345 mol/L x 0.500 L = 0.1725 moles
0.1725 mols x 98.08 g/mol = 16.92 g (not sure where you got 16.56 g)
To answer the part about NaOH, look at the balanced equation
2NaOH + H2SO4 ==> Na2SO4 + 2H2O
moles H2SO4 = 25 ml x 1 L/1000 ml x 0.345 mol/L = 0.008625 mols
mols NaOH needed = 0.008625 mol H2SO4 x 2 mol NaOH/ mol H2SO4 = 0.01725 mols
mls NaOH = 0.01725 mols x 1 L / 0.250 mols = 0.069 L = 69 mls NaOH needed