J.R. S. answered 12/16/21
Ph.D. University Professor with 10+ years Tutoring Experience
%(w/v) means grams solute per 100 mls solution.
g solute = 25.0 g
vol solution = 83.0 ml
%(w/v) = 25.0/83.0 (x100) = 30.1% w/v
molarity = mols solute per liter soln
mols = 25.0 g NaCl x 1 mol/58.4 g = 0.428 mols
liters of soln = 83.0 mls x 1 L/1000 ml = 0.083 L
molarity (M) = 0.428 mol / 0.083 L = 5.16 M