J.R. S. answered 12/06/21
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When the temperature and pressure are constant, you can use volume (L) the same way you would use moles in a stoichiometry problem. Thus...
2PCl3(g) + O2(g) ⟶ 2POCl3(g) ... balanced equation
4.8 L PCl3 x 1 L O2 / 2 L PCl3 = 2.4 L O2 needed