J.R. S. answered 11/20/21
Ph.D. University Professor with 10+ years Tutoring Experience
We can calculate the theoretical pH of each solution, and then you'd have to compare that to what you actually observed using the pH meter. Many things can cause the pH of the solution to be slightly different between actual and calculated.
For 0.1 M HCl:
pH = -log [H+] = -log 0.1
pH = 1.0
For 0.1 M acetic acid (CH3COOH; HAc):
HAc ==> H+ + Ac-
Looking up the Ka for acetic acid, I find it to be 1.76x10-5
Ka = [H+][A-] /[HA] = (x)(x) / 0.1
1.76x10-5 = x2 / 0.1
x2 = 1.76x10-6
x = [H+] = 1.33x10-3 M
pH = -log 1.33x10-3
pH = 2.9