J.R. S. answered 11/08/21
Ph.D. University Professor with 10+ years Tutoring Experience
To find the empirical formula, we want to find the number of moles of (whole numbers) of each element.
Assume 100 g of unknown;
For C: 85.6 g C x 1 mol C / 12 g = 7.13 mols C
For H: 14.4 g H x 1 mol H / 1 g = 14.4 mols H
Divide both by 7.13 to get whole numbers...
C = 7.13 mols / 7.13 = 1 mol C
H = 14.4 mols / 7.13 = 2 mol H
Empirical formula = CH2
To find the molecular formula, we find how many of the empirical formula fit into the molar mass of the molecular formula. Molar mass CH2 = 14
84.2 / 14 = 6
Molecular formula = 6 x the empirical formula = C6H12