J.R. S. answered 11/06/21
Ph.D. University Professor with 10+ years Tutoring Experience
2AgNO3(aq) + CaCl2(aq) ==> 2AgCl(s) + Ca(NO3)2(aq) ... balanced equation
mols AgNO3 present = 31.50 ml x 1 L / 1000 ml x 0.0150 mol/L = 0.0004725 mols AgNO3 = mols Ag+
mols CaCl2 needed = 0.0004725 mol AgNO3 x 1 mol CaCl2 / 2 mol AgNO3 = 0.0002363 mols CaCl2 needed
grams CaCl2 needed = 0.0002363 mols x 110.98 g/mol = 0.0262 g CaCl2 (3 sig.figs.)