J.R. S. answered 10/29/21
Ph.D. University Professor with 10+ years Tutoring Experience
Yes, anhydrous means without any water attached, so the molar mass of CaCl2 is meant at the anhydrous salt, and is 111 g / mol.
2NaOH(aq) + CaCl2(aq) ==> 2NaCl(aq) + Ca(OH)2(s) ... balanced equation
Finding the limiting reactant. One easy way is to divide the moles of each reactant by the corresponding coefficient in the balanced equation.
NaOH: 80.0 g x 1 mol / 40 g = 2 mols (÷2 -> 1)
CaCl2: 90.0 g x 1 mol / 111 g = 0.81 mols (÷1 -> 0.81)
Limiting reactant is CaCl2 b/c 0.81 is less than 1.
The product containing Ca is the Ca(OH)2, with a molar mass of 74.1 g/mol
Finding the amount of Ca(OH)2 formed:
0.81 mols Ca(OH)2 x 1 mol Ca(OH)2 / mol CaCl2 x 74.1 g / mol = 60.1 g Ca(OH)2