J.R. S. answered 10/24/21
Ph.D. University Professor with 10+ years Tutoring Experience
You didn't provide "the equation below" so I'll use my own.
moles H3PO4 = 25 m x 1 L/1000 ml x 1.0 mol/L = 0.025 moles H3PO4
moles NaOH = 75 ml x 1 L/1000 ml x 1.0 mol/L = 0.075 moles NaOH
Reaction: H3PO4 + 3NaOH ==> Na3PO4 + 3H2O
moles of reaction = 0.025 moles
q = Ccal x ∆T
q = heat = ?
Ccal = calorimeter constant = 78.5 J/º
∆T = change in temperature = 28.2 - 22.6 = 5.6º
q = 78.5 J/º x 5.6º = 439.6 J
∆Hrxn = 439.6 J / 0.025 moles = 17,584 J/mol = 17.6 kJ/mol