J.R. S. answered 10/20/21
Ph.D. University Professor with 10+ years Tutoring Experience
B2H6(g) + 3 O2(g) → B2O3(s) + 3 H2O(g) ∆H = -2035 kJ
This tells us that for every 1 mol of B2O3 that is formed in this reaction, 2035 kJ of heat are liberated.
So, we need to find out how many moles of B2O3 have been formed under the given conditions.
To do this, we must first find the limiting reactant, between B2H6 and O2. One easy way to do this is to divide the moles of each by their corresponding coefficient in the balanced equation. Thus...
B2H6: 8.64 g B2H6 x 1 mol/27.67 g = 0.312 mols (÷1 -> 0.312)
O2: 7.18 g O2 x 1 mol / 32 g = 0.224 (÷3 -> 0.074)
O2 is LIMITING (0.074 is less than 0.312)
Now, we use moles of O2 to find moles of B2O3 formed:
0.224 mols O2 x 1 mol B2O3 / 3 mols O2 = 0.0747 mols B2O3 formed
Finally, we compute the amount of heat released:
0.0747 mols B2O3 x 2035 kJ / mol B2O3 = 152 kJ of heat released
You could also report this as -152 kJ (the negative sign means heat is released)