In this case, it may be easier to find the complement of the question. That is:
You are asked to find P(Sum > 4), this is equal to 1 - P(Sum < 4).
Consider the following (Dice 1, Dice 2):
(1, 1)
(1, 2)
(2, 1)
P(Sum < 4) = 3/36 = 1/12
These are the only combinations for the dice to sum to a value less than 4. Therefore, of the 36 possible combinations, 3 are removed, leaving you with 33/36 possible combinations.
P(Sum > 4) = 1 - P(Sum <4) = 1 - (1/12) = 11/12 (which is exact)
You could also say P(Sum > 4) ~ 0.917 or 91.7%