J.R. S. answered 07/29/21
Ph.D. University Professor with 10+ years Tutoring Experience
Since molarity is defined as moles of solute per liter of solution, we need to find both values.
moles solute = 525 g NaCl x 1 mol NaCl / 58.4 g = 8.9897 mols
volume in liters = 800 ml x 1 L / 1000 ml = 0.800 L (assuming the volume didn't change when adding NaCl which is not a valid assumption - see below).
Molarity = 8.9897 mols / 0.800 L = 11.24 M = 11.2 M (3 sig. figs.)
NOTE: since molarity is based on 1 liter of solution, not 1 liter of added solvent, you'd have to assume that the final volume of solution is 800 ml and that the 525 g of NaCl didn't increase the volume. This is not the case, so this answer is just an exercise and not a valid response.
Perhaps, you wanted to know the molality which is moles solute per kg of solvent. In that case, we have...
8.9897 mols solute
0.800 kg of solute (assuming a density of 1g/ml for water)
m = molality = 11.2 m