Martin P. answered 07/23/21
graduate chemistry work, Doctorate degree, Former College Professor
A) you are given the concentration of HBr acid as 0.95 M
HBr is one of the seven inorganic strong acids that dissociates completely into its ions,
HBr -----> H3O+ + Br-
this means HBr with a Molarity of 0.95M has a H3O+ concentration of 0.95 mol/L (M)
To find the {OH-} you take the following steps:
1) find the pH of the HBr, convert to that to the pOH and then take the antilog of the -pOH to obtain the {OH-}
pH = -log {H+} = -log 0.95 = 0.022
pH + pOH = 14: 0.022 + pOH = 14
pOH = 14 - 0.022 = 13.978
{OH-} = antilog -pOH
{OH-} = antilog -13.978 = 1.052 x 10-14 M
B) Given the Molarity of Ca(OH)2 = 0.012 M
Ca(OH)2 is a strong base meaning it dissociates completely into its respective ions,
Ca(OH)2-----> Ca+2 + 2OH-
Note that for every one mole of Ca(OH)2 you form one mole of Ca+2 and 2 moles of OH-
Therefore you must multiply the Molarity of Ca(OH)2 by x 2 to obtain the Molarity of {OH-}
{OH-} = 0.012 x 2 = 0.024 M
1) To find the H3O+ concentration, {H+}, the steps are very similar to part A)
You find the pOH, subtract that number from 14 to obtain the pH, then take the antilog of the -pH and that will give you your {H3O+}
pOH = -log {OH-}
pOH = -log 0.024 = 1.62
now use the relationship: pH + pOH = 14
1.62 + pH = 14
pH = 14 - 1.62 = 12.38
final step: take the antilog of the -pH to get the {H3O+}
{H3O+} = antilog -12.38 = 4.169 x 10-13 M (mol/L)