I'll use T to stand for theta:
2sin(T) - 1 = csc(T)
Replace csc(T) with 1/sin(T)
2sin(T) - 1 = 1/sin(T)
Multiply both sides of equation by sin(T)
2sin2(T) - sin(T) = 1
Set equation equal to 0
2sin2(T) - sin(T) - 1 = 0
Factor
(2sin(T) + 1)(sin(T) - 1) = 0
Set each factor equal to zero and solve.
2sin(T) + 1 = 0 implies that sin(T) = -1/2. Using the unit circle, we know that T = 210 and 330 degrees
sin(T) - 1 = 0 implies that sin(T) = 1. Again from the unit circle, we knot T = 90 degrees
Hence, all three solutions are T = 90, 210, and 330 degrees.