J.R. S. answered 04/26/21
Ph.D. University Professor with 10+ years Tutoring Experience
If NaOH (aq) is added, the pH will increase only slightly because the OH− ions will react with HC2H3O2 molecules.
Explanation:
The mixture of HC2H3O2 and C2H3O2- creates a buffer solution. If you add NaOH, or simply OH-, it will react with the acid, HC2H3O2 to produce H2O and C2H3O2-. This is why the first answer is correct.
The 2nd answer is not correct, because if HCl is added the pH will decrease slightly because the H+ will react with the C2H3O2- to produce HC2H3O2 (a weak acid). It won't react with HC2H3O2 .