Henoch M.

asked • 04/20/21

Color change during a titration

Good day


i have two questions:

1) I want to perform a standardization of H2SO4 against standardized NaOH using phenolphthalein indicator, which solution is gonna be in the burette? is it the H2SO4 or the NaOH that will be in the burette? and what is the color change for this titration?


2) I want to perform a titration of aspirin containg Acetylsalicylic Acidn against H2SO4 using phenol red as an indicator, what is the color change in this case?

  


1 Expert Answer

By:

Henoch M.

In my experimental design it says the following : Accurately weigh 3 or 4 tablets (or ca. 1.5 g of sample if supplied in powder form) into an Erlenmeyer flask, add accurately between 25 mL and 35 mL of the ca. 1 M NaOH solution (by burette) and 20 mL of distilled water to the flask. (Remember to write down the exact volume of ca. 1 M NaOH added.) 2. Simmer gently for 10 minutes to hydrolyse the acetyl salicylic acid. 3. After cooling the mixture, transfer it quantitatively to a 250 mL volumetric flask and dilute to the mark with distilled water. 4. Titrate in triplicate three 25.00 mL aliquots of this solution against the ca. 0.05 M H2SO4, after the addition of a few drops of phenol red to each flask.' what will be the color change in this case?
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04/20/21

J.R. S.

tutor
This is a back-titration. When you add NaOH to the original sample of aspirin (an acid), you are neutralizing the acid but are also adding EXCESS NaOH. Then when you transfer that and dilute it, you then BACK TITRATE the excess NaOH with H2SO4. If you know exactly how many moles of NaOH were ORIGINALLY added and you determine the excess NaOH left over (by titrating with H2SO4), you can calculate the moles NaOH used to react with the aspirin in the original sample. I hope this is clear because it's a little difficult to explain in writing. Look up or google search "back titration" and you'll see what this is about. Let me know if you have other questions.
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04/20/21

Henoch M.

thank you, this was very helpful
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04/20/21

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