J.R. S. answered 03/09/21
Ph.D. University Professor with 10+ years Tutoring Experience
First, we must balance the reaction:
8CO2(g) + 10H2O(g) ==> 2C4H10(l) + 13O2(g) ... balanced equation
Next, we will find the moles of both reactants, i.e. moles CO2 and moles H2O present. To do this, we will employ the ideal gas law PV = nRT and solve for moles, n = PV/RT
P = 730 mm Hg x 1 atm/760 mm Hg = 0.961 atm
T = 33 + 273 = 306K
R = 0.0821 Latm/Kmol
For CO2: n = (0.961)(4.1)/(0.0821)(306) = 0.157 moles CO2
For H2O: n = (0.961)(2.1)/(0.0821)(306) = 0.080 moles H2O
Since it takes 10 moles H2O for each 8 moles CO2, clearly H2O is present in limiting supply and it alone will dictate how much O2 can be formed.
Final step is to now convert moles of H2O present to moles of O2 formed, and then to grams of O2 formed:
0.080 moles H2O x 13 moles O2 / 10 moles H2O = 0.104 moles O2 formed
0.104 moles O2 x 32 g /mol = 3.3 g O2 formed