J.R. S. answered 03/09/21
Ph.D. University Professor with 10+ years Tutoring Experience
Mole fraction of a gas is simply the moles of that gas divided by the total moles of all gases present.
Total moles = 0.25 + 2.46 + 5.46 = 8.17 moles
mol fraction Ar = 5.46 / 8.17 = 0.668