100%-32.02%O=67.98%V
Divide by the molar mass:
V: 67.98/50.942=1.3345mol
O:32.02/16.00=2.0013mol
Divide by the smaller mol value
V:1.3345/1.3345=1
O:2.0013/1.3345=1.4997=1.5
multiply both values by 2 to make them both whole numbers and get rid of the .5
V:1*2=2
O:1.5*2=3
V2O3