Hello, Katrina,
Balancing chemical equations requires some art and patience, but the approach I show here helps build those traits. The thing to remember is that the equation can be literally read as single molecules, made up of individual atoms.
A good way to start is to set up a table to keep track of all the atoms. Leave room in the equation to add a number for the number of atoms of each component under that compound. Then check to see if the sum of all the atoms coming in is equal to the sum of all the atoms leaving as products. There isn't room here for my table, but hopefully you can visualize it.
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In your problem:
____Al + ____O2 → ____Al2O3
Start with the most complex molecule, Al2O3. Since we need a whole molecule, let's assign a 1 as it's coefficient. That tells us we need 2 Al atoms coming in, so assign a 2 for Al. But now I'm startled to find that there are three oxygens in the product. Oxygen is diatomic, so it must enter as O2. I can't assign a whole number to O2 that will result in an odd number of oxygens. In this case, let's go back and make it two Al2O3 molecules. We are now here:
____Al + ____O2 → _2_Al2O3
Then add the coefficients for Al and O2 that will provide 4 Al and 6 O atoms.
__2_Al + _3__O2 → __2_Al2O3
Double check the result. Two Al atoms on both sides. Six O atoms on both sides. It works!
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These take some practice, so keep at it. One hint: if you have a problem with even/odd numbers like we had above, you can work with fractions as a holding pattern until the equation is balanced. You then multiply them all by the smallest number that would make them whole numbers. In this problem, for example:
____Al + ____O2 → _1_Al2O3 [Note to self: "Darn, I've got an odd number of oxygens in the product. Well, I'm going to try it anyway."]
_1__Al + _1/2_O2 → _1_Al2O3 ["The teacher won't like this, but it works. I'll foot him/her - I'll just multiply everything by 2 to make the 1/2 a whole number."]
_2_Al + _1_O2 → _2_Al2O3 ["This will work, and he./she will never know."]
Have fun,
Bob