J.R. S. answered 01/18/21
Ph.D. University Professor with 10+ years Tutoring Experience
S2O32¯ + I3¯ ---> I¯ + S4O62¯
+2..-2....0..-1.....-1...+2.5..-2.....
S: +2 to +2.5 = ∆+0.5 = oxidation
I: 0 to -1 = ∆-1 = reduction (but I3- can be viewed as I2 + I- so takes 2e- to reduce I2 to 2I-)
2S2O32- ===> S4O62- + 2e-
I3- + 2e- ===> 3I-
2S2O32- + I3- ===> S4O62- + 3I- ... balanced equation