The angle for the direction of vector, v, is θ = tan-1(vy/vx) with the correction of +/- π for vx < 0. In this case, you are given vy as vsin(θ) and vx as vcos(θ), so you can just read off the angle.
The first vector has angle 5π/6 and the second has angle π/4. The angle between them should be clear.
Take care.