J.R. S. answered 12/16/20
Ph.D. University Professor with 10+ years Tutoring Experience
N2(g) + 3H2(g) <==> 2NH3(g) ... ∆H = -92.4 kJ and K = 1.45x10-5
a) One way to increase production of NH3 would be to lower the temperature. Because the ∆H is negative, this means that heat is given off by the reaction and one can view heat as a product. Removing a product (heat) would pull the reaction toward the product side thus making more NH3(g). This is according to Le Chatelier.
b) ∆G = -RT ln K
∆G = ?
R = gas constant = 8.314 J/Kmol = 0.008314 kJ/molK
T = temperature in K = 500K
K = equilibrium constant = 1.45x10-5
Solving for ∆G, we have...
∆G = -(0.008314)(500)(-11.1)
∆G = +46.1 kJ
This value supports the known equilibrium constant of the reaction because they BOTH suggest that the reaction is NOT SPONTANEOUS. A positive ∆G tells us the reaction is not spontaneous and a K value <1 also tells us the same.