J.R. S. answered 12/03/20
Ph.D. University Professor with 10+ years Tutoring Experience
I and III look like plausible resonance contributions for NCNH-
II doesn't appear correct because of connectivity, and IV doesn't look favorable because of the formal charge distribution on both nitrogen atoms (-2 and +1).

J.R. S.
12/03/20
Ina S.
Thank you so much!12/03/20