J.R. S. answered 11/23/20
Ph.D. University Professor with 10+ years Tutoring Experience
First, let's find the order of the reaction with respect to A and B:
Comparing Expt. 1 and 2 where [A] doubles and [B] remains the same, the rate doubles. This tells us that the reaction is FIRST ORDER WITH RESPECT TO A
Comparing Expt. 1 and 3 where [B] triples and [A] remains the same, the rate triples. This tells us that the reaction is FIRST ORDER WITH RESPECT TO B
We can now write the rate law as...
rate = k[A][B]
From the rate law and using any one of the experiments, we can find the value of k as follows:
using experiment 1, rate = 2.0x10-3 M/s and we know that rate = [A][B], so...
2.0x10-3 M/s = k[0.50 M][0.60 M]
k = 2.0x10-3 M/s / [0.50 M][0.60 M]
k = 6.67x10-3 M-1s-1