J.R. S. answered 11/16/20
Ph.D. University Professor with 10+ years Tutoring Experience
a) You didn't provide units for the 76.6 so I'll assume that it means 76.6 ml.
69.9 % (v/v) means 69 ml alcohol/100 ml of solution. Thus, 69.9 ml alc/100 ml soln x 76.6 ml = 53.5 ml alc.
b) You didn't provide units for the 3.27 nor for 53.0 so I'll assume they are M and grams respectively. See how important it is to include units, because when one assumes, ..... never mind.
53.0 g x 1 mol/174.01 g = 0.305 moles
(x L)(3.27 mol/L) = 0.305 moles
x = 0.0931 liters
If this is incorrect, it's because you didn't provide units.