J.R. S. answered 11/13/20
Ph.D. University Professor with 10+ years Tutoring Experience
2 NaHCO3(s) ==> Na2CO3(s) + CO2(g) + H2O(l) ... balanced equation
To find the % yield, we need to first find the THEORETICAL yield. This is done from the stoichiometry of the balanced equation and using dimensional analysis.
Theoretical yield of Na2CO3(s):
1.49 g NaHCO3 x 1 mol NaHCO3 / 84.0 g x 1 mol Na2CO3 / 2 mol NaHCO3 x 106 g/mol = 0.940 g
So, just as you stated, the yield of 4.66 g IS NOT POSSIBLE, and so the calculated % yield will be greater than 100%, which again, is not possible. But if you did calculate it, just as an exercise, it would be
4.66 g / 0.940 g (x100) = 496%