J.R. S. answered 11/05/20
Ph.D. University Professor with 10+ years Tutoring Experience
Since the system is at STP, you don't have to use the ideal gas law (although there's nothing wrong with doing it that way). To save time, you can use the fact that at STP, 1 mol of gas = 22.4 L.
456 ml = 0.456 L
0.456 L x 1 mol/22.4 L x 46 g NO2/mol NO2 = 0.936 g NO2