J.R. S. answered 10/27/20
Ph.D. University Professor with 10+ years Tutoring Experience
Combustion reactions require oxygen gas.
C8H18 + O2 ==> CO2 + H2O ... UNBALANCED
C8H18 + O2 ==> 8CO2 + H2O ... Carbons are balanced
C8H18 + O2 ==> 8CO2 + 9H2O ... Carbons and hydrogens are balanced
C8H18 + 12.5 O2 ==> 8CO2 + 9H2O ... Carbons, hydrogens and oxygens are balanced, BUT...
To get rid of the fraction (12.5) applied to the O2, multiply everything by 2 to arrive at...
2C8H18 + 25 O2 ==> 16CO2 + 18H2O ... BALANCED EQUATION