J.R. S. answered 09/23/20
Ph.D. University Professor with 10+ years Tutoring Experience
You really always need to write the correctly balanced equation FIRST, before answering these types of questions. You MUST look at the mole ratio of the reactants and the products.
Fe(s) + 2HCl(aq) ==> FeCl2(aq) + H2(g) ... balanced equation (note mole ratios)
First, we must find the limiting reactant:
For Fe(s): 18.7 g Fe x 1 mol Fe/55.8 g x 1 mol FeCl2/mol Fe x 127 g/mol FeCl2 = 42.6g FeCl2 formed
For HCl(aq): 28.8 g HCl x 1 mol HCl/36.5 g x 1 mol FeCl2/2 mol HCl x 127 g/mol FeCl2 = 50.1 g FeCl2 formed
LIMITING REACTANT IS Fe(s)
The maximum amount of FeCl2 formed is that obtained from the limiting reactant = 42.6 g FeCl2 formed
Excess reactant (HCl) left: we started with 28.8 g x 1 mol/36.5 g = 0.789 moles. For each mol of Fe, we used 2 moles of HCl. The moles of Fe used is 18.7 g x 1 mol/55.8 g = 0.335 moles Fe. So moles of HCl used is
2 x 0.335 = 0.670 moles HCl used (SEE WHY MOLE RATIOS ARE IMPORTANT?)
Moles HCl left over = 0.789 mol - 0.670 = 0.119 moles HCl left over
mass HCl left over = 0.119 moles HCl x 36.5 g/mol = 4.34 g HCl left over