To do this manually, build a table where the first column is the list of numbers. Calculate the mean by adding all the numbers and dividing by the number of numbers (in this case there are 6 numbers). We define the numbers as values of "x" and the mean as x-bar.
x
---
2
3
5
5
3
6
---
sum = 24, x-bar = 24/6 = 4
Now, add a second column that is x-bar subtracted from the x-value (so x - x-bar) like this:
x (x - x-bar)
----------------
2 -2
3 -1
5 1
5 1
3 -1
6 2
Now add a third column that is the square of the second column (so (x - x-bar)2 like this:

The sum of the squares is typically the sum of the third column. Adding the numbers in column 3 gives us 12 so SS = 12
The Variance (for a sample, which this is defined as a sample), is SS/(n - 1) so 12/(6 - 1) = 12/5 = 2.4
The standard deviation is the square root of the Variance so √2.4 = 1.549193.