J.R. S. answered 08/31/20
Ph.D. University Professor with 10+ years Tutoring Experience
CH4 + CCl4 ==> 2CH2Cl2 ... balanced equation
0ºC and 1 atm = STP and at STP 1 mol of gas = 22.4 L
89.5 L CCl4(g) x 1 mol/22.4 L = 3.995 moles CCl4
moles CH4 = 3.995 mol CCl4 x 1 mol CH4/1 mol CCl4 = 3.995 mol CH4 = 3.40 moles CH4 (3 sig.figs.)