J.R. S. answered 06/16/20
Ph.D. University Professor with 10+ years Tutoring Experience
Molarity is defined as moles of solute per liter of solution. Since we are dealing with 2 liquids, we take the one present in greater amount as the solvent (CCl4) and the one present in lower amount as the solute (C6H6).
4.31% m/v means 4.31 g C6H6 / 100 ml CCl4 = 43.1 g C6H6 / L
Converting this to moles / L we have...
43.1 g C6H6 x 1 mol/78.11 g = 0.552 moles C6H6 per L of CCl4
Molarity (M) = moles / L = 0.552 moles / 1 L = 0.552 M