J.R. S. answered 05/29/20
Ph.D. University Professor with 10+ years Tutoring Experience
An oxidizing agent is an agent that itself becomes reduced, i.e. it gains electrons.
A reducing agent is an agent that itself becomes oxidized, i.e. it loses electrons.
2MnO4- + 5H2SO3 --> 2Mn2+ + 5SO42- + 4H+ + 3H2O
S on the left side of the equation has an oxidation number of 4+. On the right side it has an oxidation number of 6+. Thus, S has lost 2 electrons, has become more positive and thus has been oxidized. This makes it a reducing agent. So, the reducing agent in this reaction is H2SO3.
Mn on the left side of the equation has an oxidation number of 7+. On the right side it has an oxidation number of 2+. Thus, Mn has gained 5 electrons, has become more negative (less positive) and thus has been reduced. This makes it an oxidizing agent. So, the oxidizing agent is MnO4-