J.R. S. answered 05/21/20
Ph.D. University Professor with 10+ years Tutoring Experience
If the temperature and pressure remain constant (as in the current problem), then adding gas must increase the volume. If not, then the pressure would certainly increase. If you look at the ideal gas law, PV = nRT, you see that if the T and P are constant, ( and R is also a constant), then V is proportional to n (moles of gas). Thus, we can set up a proportion ...
V1/n1 = V2/n2
V1 = initial volume = 7.00 L
n1 = initial number of moles = 78 g Ar x 1 mol/40 g = 1.95 moles
V2 = final volume = ?
n2 = final number of moles = 96 g Ar x 1 mol/40 g = 2.4 moles
7.00 L/1.95 moles = V2/2.4 moles
V2 = 8.62 L
NOTE: the number of moles increased by 2.4/1.95 = 1.23 x. The volume also increased by 8.62 L/7.00 L = 1.23 x. A direct relationship.