J.R. S. answered 05/08/20
Ph.D. University Professor with 10+ years Tutoring Experience
S2O82-(aq) ==> SO42-
S2O82-(aq) ==> 2SO42- ... to balance the S atoms
S2O82-(aq) ==> 2SO42- + 4H2O ... to balance the O atoms
S2O82-(aq) + 8H+ ==> 2SO42- + 4H2O ... to balance the H atoms
S2O82-(aq) + 8H++ 10e- ==> 2SO42- + 4H2O ... to balance the charge & this is the balanced half reaction
Cr2O72- ==> Cr3+
Cr2O72- ==> 2Cr3+ .. to balance Cr atoms
Cr2O72- ==> 2Cr3+ + 7H2O .. to balance O atoms
Cr2O72- + 14H+ ==> 2Cr3+ + 7H2O .. to balance H atoms
Cr2O72- + 14H+ + 6e- ==> 2Cr3+ + 7H2O .. to balance charge & this is the balanced half reaction
Do the last one the same way. Good luck.