J.R. S. answered 05/01/20
Ph.D. University Professor with 10+ years Tutoring Experience
Look at the balanced equation for the reaction:
H2SO4 + 2NaOH ===> Na2SO4 + 2H2O ... balanced equation
The coefficients tell you the mole ratio. So, 1 mole H2SO4 reacts with 2 mol NaOH to => 1mol Na2SO4 and 2 mol H2O.
Since it takes twice as many moles of NaOH, you can tell that NaOH is limiting because you start with 50 mol NaOH and 45 mol H2SO4. Clearly not twice as much NaOH as H2SO4.
Using dimensional analysis we can find grams of H2O produced from 50 mols NaOH:
50 mol NaOH x 2 mol H2O/2 mol NaOH = 50 moles H2O formed
50 moles H2O x 18 g/mole H2O = 900 g H2O formed
To find moles of excess reactant, again we can use dimensional analysis along with the mole ratios of the balanced equation:
50 mol NaOH x 1 mol H2SO4/2 mol NaOH = 25 moles H2SO4 used up
moles H2SO4 remaining = 45 - 25 = 20 moles H2SO4 remaining