J.R. S. answered 04/20/20
Ph.D. University Professor with 10+ years Tutoring Experience
HClO4 is a strong acid, so the pH will be the negative log of the [H+] concentration.
In this case, pH = 3.2 indicates a [H+] of 1x10-3.2 M = 6.3x10-4 M
Now we can use V1M1 = V2M2 to find the volume of 9.2 M HClO4 to make 500 ml of 6.3x10-4 M HClO4
(x ml)(9.2 M) = (500 ml)(6.3x10-4 M)
x = 0.0342 mls of 9.2 M HClO4 is needed