J.R. S. answered 04/17/20
Ph.D. University Professor with 10+ years Tutoring Experience
Cu2+ + 2e- ===> Cu(s) Eº = -0.337 V
Na+ + e- ===> Na(s) Eº = -2.71 V
Since reduction potential for Cu2+ is greater than that for Na+, Cu2+ will be reduced at the cathode and Na will be oxidized at the anode.
Half reactions:
Cu2+ + 2e- ===> Cu(s) ... reduction (cathode)
Na(s) ===> Na+ + e- ... oxidation (anode)
Balanced overall reaction:
Cu2+ + 2Na(s) ==> Cu(s) + 2Na+
Cell Potential:
Eºcell = Eºcathode - Eºanode = -0.337 - (-2.71)
Eºcell = 2.37 V (spontaneous because it is positive)