J.R. S. answered 04/22/20
Ph.D. University Professor with 10+ years Tutoring Experience
You didn't describe the experiment, but it seems as though the gas (CO2) was collected over water, and you are asked to find the pressure of CO2. When a gas is collected over water, the vapor pressure of the water must be deducted from the total pressure to obtain the pressure of the collected gas.
756.92 mm Hg - 18.7 mm Hg = 738.2 mm Hg = pressure of CO2