First you want to use the Ideal Gas Law to calculate the Moles of the Gas
PV = nRT
n = PV / RT
n = (2.733 atm x 1.00 L) / (0.08206 L*atm / mol*K * 293.15 K) = 0.1136 mol
Then to find the Molar Mass you want to take the given mass of the substance and divide by the number of moles
Molar Mass (M) = 5.00 g / 0.1136 mol = 44.01 g/mol
meaning that the molar mass of the unknown gas is approximately 44.01 g/mol

J.R. S.
08/26/25