J.R. S. answered 02/28/20
Ph.D. University Professor with 10+ years Tutoring Experience
Use dimensional analysis:
each molecule of P4O10 contains 4 atoms of P and 10 atoms of O for a total of 14 atoms/molecule.
1.42x1027 P4O10 molecules x 14 atoms/molecule = 1.99x1028 atoms
Each formula unit of PbCl4 contains 1 Pb atom and 4 Cl atoms for a total of 5 atoms/molecule
7.743x1020 formula units x 5 atoms/formula unit = 3.872x1021 atoms