J.R. S. answered 02/14/20
Ph.D. University Professor with 10+ years Tutoring Experience
12HClO4 (aq) + P4O10 (s) ==> 4H3PO4 (aq) + 6Cl2O7 (l) ... balanced equation
molar mass Cl2O7 = 70.9 + 111.99 = 182.9 g/mol
moles Cl2O7 produced = 68.8 g x 1 mol/182.9 g = 0.376 moles
moles P4O10 consumed = 0.376 moles Cl2O7 x 1 mol P4O10/6 mol Cl2O7 = 0.0627 moles P4O10 consumed
mass H3PO4 produced = 0.376 mol Cl2O7 x 4 mol H3PO4/6 mol Cl2O7 x 98 g/mol = 24.6 g H3PO4
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