J.R. S. answered 01/22/20
Ph.D. University Professor with 10+ years Tutoring Experience
First, write the correctly balanced equation for the reaction taking place:
Mg(s) + 2HCl(aq) ==> MgCl2(aq) + H2(g)
Next, since HCl is present in excess, there is no need to find the limiting reactant, as it will be Mg.
So, find moles of Mg, then moles H2 and finally the volume of H2.
Moles Mg = 16.7 g Mg x 1 mol Mg/24.305 g = 0.6871 moles Mg
Moles H2 produced = 0.6871 moles Mg x 1 mol H2/1 mol Mg = 0.6871 moles H2
To find volume of H2, we use the ideal gas law; PV = nRT and solve for V (volume):
V = nRT/P
n = moles H2 = 0.6871 moles
R = gas constant = 0.08206 Latm/Kmol
T = temperature in K = 25.0 + 273 = 298K
P = pressure = 1.11 atm
V = (0.6871)(0.08206)(298)/1.11 = 15.1 L (to 3 significant figures)